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个人信息

姓名:郭瑞

学历:博士

职称:研究员

E-mailruiguo@ccnu.edu.cn

课题组网站:https://www.x-mol.com/groups/Zhang_Guozhu

 

教育与研究经历

郭瑞1989年出生于山东寿光,现任77779193永利官网研究员

20233-至今华中师范大学77779193永利官网,研究员,硕士生导师

202012-20233,中国科学院上海有机化学研究所,助理研究员

20189-20209月,美国匹兹堡大学,化学系,博士后,合作导师:Prof. Yiming Wang

20159-20186月,中国科学院上海有机化学研究所,博士,导师:张国柱研究员

20129-20156月,兰州大学,化学化工学院, 硕士,导师:翟宏斌教授

20089-20126,中国海洋大学,医药学院,学士

 

研究领域与兴趣

1. 过渡金属催化有机合成方法学

2. 自由基介导的碳氢键官能团化反应

3. 有机氟化学

4. 生物活性分子的合成与功能优化

 

承担项目与课题信息

1. 国家自然科学基金青年项目,2024.01-2026.12,主持

2. 华中师范大学高层次人才启动经费,2023.03-2028.03,主持

 

学术成果(代表性论文)

1. J. Li#, S. Li#, G.-H. Cui, K. Yuan, C. Wang, C. Yang, G. Zhang*, R. Guo*, Photoinduced Copper-Catalyzed Regio- and Enantioselective Alkynylation of Epoxides. ACS Catal. 2024, 14, 7553–7561. (# contributed equally)

2. K.-Q. Tian#, S.-J. Zhang#, J. Zhao, G.-Y. Duan, Q.-L. Wang, G.-H. Cui, R. Guo*, H.-S. Li*, Regio- and Diastereoselective Highly Strained Alkylidenecyclobutane Isomerization/Hydroacylation: Synthesis of Multisubstituted Cyclobutanes with Consecutive Stereocenters.  ACS Catal. 202414, 1505−1513. (# contributed equally)

3. J. Zheng, H. Zhang, S. Kong, Y. Ma, Q. Du, B. Yi, G. Zhang*, and R. Guo*, Copper-Catalyzed General and Selective α-C(sp3)–H Silylation of Amides via 1,5-Hydrogen Atom Transfer. ACS Catal. 2024, 14, 1725–1732.

4. J. Lu#, M. Zhang#, X. Zheng, P. Shen, Y. Xu, Q. Zhang, Y. Tang, G. Zhang*, and R. Guo*, Rhodium(I)-Catalyzed Enantioselective Ring-Opening and Isomerization of Cyclobutanols through a (Z)-Unsaturated Ketone Intermediate. Org. Lett. 202325, 5151–5156. (# contributed equally)

5. Rui Guo, Chao Shu*, Guozhu Zhang*, “Photoinduced Metal-free α-C–H Borylation of Aliphatic Amines”, Chem, 2022, 8, 2902-2904. (Previews)

6. Rui Guo, Haijing Xiao, Sijia Li, Yixin Luo, Jiahui Bai, Mengzhen Zhang, Xiaotian Qi*, Yinlong Guo*, Guozhu Zhang*, “Photoinduced Copper-Catalyzed Asymmetric C(sp3)-H Alkynylation of Cyclic Amines by Intramolecular 1,5-Hydrogen Atom Transfer”, Angew. Chem. Int. Ed., 2022, 61, e202208232. (‡: contributed equally)

7. Rui Guo, Xiaotian Qi, Hengye Xiang, Paul Geaneotes, Ruihan Wang, Peng Liu*and Yi-Ming Wang*, “Stereodivergent Alkyne Hydrofluorination Using Protic Tetrafluoroborates as Tunable Reagents” Angew. Chem. Int. Ed., 2020, 59, 16651−16660. (‡: contributed equally) 

8. Rui Guo, Xueling Mo, Guozhu Zhang*, “Synthesis of 2-(2-Oxo-2-phenylethyl)cyclopentanone by Rhodium-Catalyzed Tandem Alkynyl Cyclobutanols Hydroacylation and Semipinacol Rearrangement” Org. Lett., 2019, 21, 1263−1267.

9. Rui Guo and Guozhu Zhang*, “Expedient Synthesis of 1,5-Diketones by Rhodium-Catalyzed Hydroacylation Enabled by C−C Bond Cleavage” J. Am. Chem. Soc., 2017, 139, 12891−12894. 

10. Rui Guo, Xinxin Zheng, Dayong Zhang*, Guozhu Zhang*, “Rhodium(I)-catalyzed stereoselective [4+2] cycloaddition of oxetanols with alkynes through C(sp3)–C(sp3) bond cleavage” Chem. Sci., 2017, 8, 3002−3006. (‡: contributed equally) 

 

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